HOME > Technologies > Column No.4 Safety and Nemoto - (2) "Gas Leakage Detectors"

Nemoto Technologies

Column No.4 Safety and Nemoto - (2) "Gas Leakage Detectors"
(January 27, 2000)

Written by; Y. Murayama
Technical Advisor
Nemoto & Co., Ltd., Tokyo

On August 16, 1980, 213 people were killed when a large gas explosion occurred in the underground shopping mall in front of the Shizuoka railway station (180 kilometers west of Tokyo). Descriptions such as, "A Pillar of Fire", "People Explode", "Station Entrance Resembles Battlefield" appeared in newspaper titles that evening. The exact cause of this disaster was never officially determined, yet in February of the following year, The Ministry of International Trade and Industry required the installation of gas leakage detectors in underground shopping malls and basements. As a result of this incident, public awareness regarding gas leakage and the need for gas leakage detectors was created.

A residential LP gas detector using a semiconductor type gas sensor had appeared on the market as early as August of 1969. In 1970, The High Pressure Gas safety Institute of Japan was formed and had begun inspection of residential LP gas detectors.

Semiconductor type LP gas detectors measure the change in electric resistance of an n-type semiconductor as LP gas molecules are absorbed on the surface of the semiconductor element. These detectors were not popular because other gases also affected the semiconductor, causing false alarms to occur with exposure to fumes from alcohol and other substances. Capitalizing on this situation, Nemoto began researching methods to make a sensor that would avoid these problems.

Nemoto became convinced that catalytic type gas sensors were the best as this type of sensor's output was directly proportionate to the concentration of gas. More importantly, catalytic type sensors had superior gas selectivity minimized the sensitivity to 'noise' gases. Nemoto began development work on a new catalytic type sensor in August 1978. After many tests on innovative catalysts and sensing materials, a highly efficient gas sensor was developed. A catalytic type gas sensor for municipal gas was made public in May 1979, and a sensor for LG gas in May 1980.

Domestic detector manufacturers were interested but hesitated to switch to Nemoto's catalytic type sensors because no data existed which could guarantee the life of the product. To obtain supporting evidence, Nemoto produced a gas detector using the new sensor and applied for UL approval. This detector received UL approval in February 1980. The number of gas detectors manufactured increased greatly after the Shizuoka explosion. Nemoto's gas sensor was developed just in time to capitalize on this growth.

UL approved gas detector NAP-7C For municipal gas NAP-8R 12V DC operated LP gas detector
UL approved gas detector NAP-7C
For municipal gas
NAP-8R
12V DC operated LP gas detector
Nemoto's gas detectors available in 1980.


Structure

Nemoto's catalytic type gas sensor has a sensing element as shown in the figure on the right. When a combustible gas contacts the surface of the element, the gas is oxidized by the action of the catalyst on the element surface, and the combustion heat heats up the core platinum filament. Since platinum's electric resistance is directly proportional to it's temperature, Nemoto's catalytic type sensors can not only detect the presence of a gas, but also measure its concentration.

The following are the features of Nemoto catalytic type sensors.

  1. Linear outputs in the range of 0 - 100% LEL (Lower Explosive Limit)
  2. Very fast response
  3. Hardly affected by ambient temperature and humidity
  4. Excellent long-term stability
  5. Excellent reproducibility
  6. The minimum detectable gas concentration is as low as 50 ppm (varies depending on gas type)
Comparison of old and new sensors
NAP-7AU (1980) NAP-55A (1995-)
Comparison of old and new sensors

Twenty years have passed since Nemoto's catalytic type sensors were developed. Currently, Nemoto sensors are widely used in gas leakage detectors, densitometers, and other measuring devices. Nemoto sensors have been well accepted by customers and have the highest reputation. Nemoto continues to develop a variety of new sensors to meet the requirements of its customers. During the past twenty years, Nemoto has manufactured over 14 million gas sensors. Nemoto will continue to develop new sensors that answer to market needs and contribute to the protection of human lives and property.



Nemoto's catalytic type sensors

Objective gases Model Features Applications
* Combustible gases
Methane
Propane
Butane
Hydrogen
Alcohol
NAP-2A High performance, Standard type Municipal gas leakagedetectors
Densitometers
NAP-55A Small-sized, Lower power consumption
NAP-50A Small-sized, Lower power consumption,
Less sensitive to alcohol
NAP-3A High performance, Standard type LP gas leakagedetectors
Densitometers
NAP-66A Small-sized, Lower power consumption
NAP-100AD Quick response, Heavy duty Industrial gas detectors
NAP-100AH Quick response, Heavy duty, High selectivity Detectors for fuel cells
*Flu gas, Incompletecombustion
CO gas
Hydrogen gas
NAP-70A Quick response, High selectivity,
Less sensitive to alcohol,
Lower power consumption
CO detectors
NAP-78A Quick response, Heavy duty, High accuracy For gas boilers
NAP-78R Quick response, Heavy duty, High accuracy

Installation ratio of Gas leakage detectors vs. number of accidents

Reference Information:
Relationship of the installation ratio of LP gas leakage detectors to the number of gas explosion accidents. (Courtesy of Japan Gas Detectors Manufacturers Association)


 

Copyright 2000 by Nemoto & Co.,Ltd , Yoshihiko Murayama, Hiro Yamamoto.